Back Cover: Visible-Light-Controlled Oxidation of Glucose using Titania-Supported Silver Photocatalysts (ChemCatChem 22/2016)
Back Cover: Visible-Light-Controlled Oxidation of Glucose using Titania-Supported Silver Photocatalysts (ChemCatChem 22/2016)
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封底：使用二氧化钛支撑的银光催化剂进行可见光控制的葡萄糖氧化 (ChemCatChem 22/2016)
DOI：
10.1002/cctc.201601429
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发表时间：
2016
期刊：
影响因子：
4.5
通讯作者：
Da Vià L
中科院分区：
文献类型：
--
作者：
Da Vià L
封面展示了利用可见光对可再生糖葡萄糖进行光催化转化，从而形成葡萄糖酸、阿拉伯糖、红细胞和甘油醛。在他们的论文全文中，L. Da viom等人描述了二氧化钛上的等离子体银纳米颗粒如何能够在室温和常压下将葡萄糖转化为小链单糖和氧化产物，选择性为98%。该反应通过α-裂解和Ruff降解的结合机制进行。该催化剂在没有活性损失的情况下被回收，并被证明具有抗浸出性。更多信息可参见L. Da viente等人在2016年第22期第3475页的论文全文（DOI: 10.1002/cctc）。201600775)。
The Cover shows the photocatalytic conversion of the renewable sugar glucose using visible light resulting in the formation of gluconic acid, arabinose, erythrose and glyceraldehyde. In their Full Paper, L. Da Vià et al. describe how plasmonic silver nanoparticles supported on titania are capable of valorising glucose to small chain monosaccharides and oxidation products with a selectivity of> 98% at room temperature and atmospheric pressure. The reaction is proposed to proceed via a combination of an α-scission and Ruff degradation mechanism. The catalyst was recycled with no loss in activity and was proven to be resistant to leaching. More information can be found in the Full Paper by L. Da Vià et al. on page 3475 in Issue 22, 2016 (DOI: 10.1002/cctc. 201600775).