Photochemical Generation of Halo(silyl)silylene : Spectroscopic Observation and Reactivity
Photochemical Generation of Halo(silyl)silylene : Spectroscopic Observation and Reactivity
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DOI：
10.1246/cl.2004.1420
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发表时间：
2004-10
影响因子：
1.6
通讯作者：
Takashi Tanaka;M. Ichinohe;A. Sekiguchi
中科院分区：
文献类型：
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作者：
Takashi Tanaka;M. Ichinohe;A. Sekiguchi
二卤代二(三叔丁基硅基)硅烷(t-Bu3Si)2SiX2(1a：X=Cl，1b：X=Br)经光化学α消除制得卤代(三叔丁基硅基)硅烷.
Dihalobis(tri-tert-butylsilyl)silanes (t-Bu3Si)2SiX2 (1a: X = Cl, 1b: X = Br) underwent photochemically α-elimination to produce halo(tri-tert-butylsilyl)silylenes, which were successively trapped ...