A pillar[5] arene-containing cross-linked polymer: synthesis, characterization and adsorption of dihaloalkanes and n-alkylene dinitriles
A pillar[5] arene-containing cross-linked polymer: synthesis, characterization and adsorption of dihaloalkanes and n-alkylene dinitriles
复制标题
柱[5]含芳烃交联聚合物：二卤代烷烃和正亚烷基二腈的合成、表征和吸附
DOI：
10.1039/c6ra15728a
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发表时间：
2016
期刊：
影响因子：
3.9
通讯作者：
Cao Derong
中科院分区：
文献类型：
--
作者：
Ye Fengqing;Wei Ruijin;Wang Lingyun;Meier Herbert;Cao Derong
以单羟基柱状[5]芳烃与氯甲基化聚苯乙烯为原料，通过Williamson反应合成了含[5]芳烃柱状交联聚合物。考察了其对客体的吸附行为。通过主客体络合，发现柱状[5]芳烃聚合物对二卤烷和二腈具有良好的吸附能力。
A pillar[5]arene-containing cross-linked polymer was synthesized via Williamson reaction involving monohydroxy pillar[5]arene with chloromethylated polystyrene. Its adsorption behavior towards guests was investigated. It was found that the pillar[5]arene-containing polymer exhibited good adsorption capacities towards dihaloalkanes and dinitriles by host-guest complexation.