Electrochemical reduction of silver vanadium phosphorous oxide, Ag(2)VO(2)PO(4): the formation of electrically conductive metallic silver nanoparticles.
Electrochemical reduction of silver vanadium phosphorous oxide, Ag(2)VO(2)PO(4): the formation of electrically conductive metallic silver nanoparticles.
复制标题
银色泛氧化物银氧化物的电化学还原,Ag(2)VO(2)PO(4):导电金属银纳米颗粒的形成。
DOI:
10.1021/cm902102k
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发表时间:
2009-10-27
影响因子:
8.6
通讯作者:
Takeuchi, Kenneth J.
中科院分区:
文献类型:
--
作者:
Takeuchi, Esther S.;Marschilok, Amy C.;Tanzil, Kevin;Kozarsky, Eric S.;Zhu, Shali;Takeuchi, Kenneth J.
As a cathode material, silver vanadium phosphorous oxide (Ag2VO2PO4) displays several notable electrochemical properties: large capacity, high current capability, and an effective delivery of high current pulses. These cell performance characteristics can be attributed to the presence of silver nanoparticles formed in-situ during the electrochemical reduction of Ag2VO2PO4. Specifically, changes in the composition and structure of Ag2VO2PO4 with reduction, especially the formation of silver nanoparticles, are detailed to rationalize a 15,000 fold increase in conductivity with initial discharge, which can be related to the power characteristics associated with Ag2VO2PO4 cathodes in primary lithium batteries.
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影响因子:
15
作者:
Ma, Hua;Zhang, Shaoyan;Chen, Jun
通讯作者:
Chen, Jun
影响因子:
6.6
作者:
Prosini, PP;Zane, D;Pasquali, M
通讯作者:
Pasquali, M
影响因子:
2.1
作者:
Park, KS;Son, JT;Kim, HG
通讯作者:
Kim, HG
DOI:
10.1039/dt9930001525
发表时间:
1993-05-21
期刊:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
影响因子:
--
作者:
KANG, HY;WANG, SL;LII, KH
通讯作者:
LII, KH
影响因子:
3.9
作者:
Franger, S;Bourbon, C;Le Cras, F
通讯作者:
Le Cras, F