ESR characterization of trans-diacidatotetrakis(pyridine)vanadium and -manganese trans-VII(py)4X2 and trans-MnII(py)4X2 (X = NCS, Cl, Br, I; py = pyridine)
ESR characterization of trans-diacidatotetrakis(pyridine)vanadium and -manganese trans-VII(py)4X2 and trans-MnII(py)4X2 (X = NCS, Cl, Br, I; py = pyridine)
复制标题
反式二酸四(吡啶)钒和锰反式-VII(py)4X2 和反式-MnII(py)4X2 的 ESR 表征（X = NCS、Cl、Br、I；py = 吡啶）
DOI：
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发表时间：
1993
期刊：
影响因子：
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通讯作者：
H. Weihe
中科院分区：
文献类型：
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作者：
C. Jacobsen;E. Pedersen;J. Villadsen;H. Weihe
合成了通式为trans-MII（py）4X 2（MII =V，Mn，Fe，Co，Ni，Ru; X=NCS，Cl，Br，I）的化合物，并以铁、钴、镍和钌化合物为固体溶剂，用ESR谱对钒（II）和锰（II）化合物进行了表征。此外，所制备的所有化合物已通过X-射线粉末衍射表征，从而在大多数情况下获得了空间群和晶胞参数
Compounds having the general formula trans-M II (py) 4 X 2 (M II =V, Mn, Fe, Co, Ni, Ru; X=NCS, Cl, Br, I) have been synthesized, and the vanadium(II) and manganse(II) compounds have been characterized by ESR spectroscopy using the iron, cobalt, nickel, and ruthenium compounds as solid solvents. Furthermore, all compounds prepared have been characterized by means of X-ray powder diffraction and thereby space groups and unit cell parameters have been obtained in most cases