Flexible microporous coordination polymers
Flexible microporous coordination polymers
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DOI：
10.1016/j.jssc.2005.05.036
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发表时间：
2005-08-01
影响因子：
3.3
通讯作者：
Kitagawa, S
中科院分区：
文献类型：
--
作者：
Uemura, K;Matsuda, R;Kitagawa, S
近十年来，人们合成了许多多孔配位聚合物，它们具有多种性质，如在空穴中储存、分离和交换客体，通过其骨架实现磁性、导电性和催化作用等。柔性多孔配位聚合物是近年来出现的一类新型多孔材料，它具有与传统多孔材料的刚性三维（3-D）框架相反的弹性客体容纳能力。这种灵活的多孔特性可以诱导高度选择性的客人容纳和磁调制，这现在可能是一类独特的实用材料。本文介绍了近年来柔性多孔配位聚合物（3-17）及其功能性质，并将其分为四类具有骨架变形的孔。(c)2005年由Elsevier Inc.出版
In a decade, many porous coordination polymers have been synthesized, providing a variety of properties ranging from storage, separation and exchange of guests in their cavities, magnetism, conductivity and catalysis by their frameworks. Recent advent of flexible porous coordination polymers, which exhibit elastic guest accommodation in contrast to rigid three-dimensional (3-D) frameworks of conventional porous materials, have acquired a position as a new class of porous materials. Such flexible porous properties induce highly selective guest accommodation and magnetic modulation, which could now be a unique class of practical materials. In this review, we introduce recent flexible porous coordination polymers (3-17) and their functional properties, categorizing with the four types of pores with framework deformation. (c) 2005 Published by Elsevier Inc.