Electrodeposition of NiFe layered double hydroxide on Ni3S2 nanosheets for efficient electrocatalytic water oxidation

Electrodeposition of NiFe layered double hydroxide on Ni3S2 nanosheets for efficient electrocatalytic water oxidation
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NiFe层状双氢氧化物在Ni3S2纳米片上的电沉积用于高效电催化水氧化

DOI:
10.1016/j.ijhydene.2020.01.113
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发表时间:
2020-03
影响因子:
7.2
通讯作者:
Baibiao Huang
Baibiao Huang
中科院分区:
工程技术2区
文献类型:
--
作者:
Zhong Liang;Peng Zhou;Zeyan Wang;Peng Wang;Yuanyuan Liu;Xiaoyan Qin;Xiaoyang Zhang;Ying Dai;Zhaoke Zheng;Baibiao Huang

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The oxygen evolution reaction (OER) plays a vital role in various energy conversion applications. Up to now, the highly efficient OER catalysts are mostly based on noble metals, such as Ir- and Ru-based catalysts. Thus, it is extremely urgent to explore the non-precious electrocatalysts with great OER performance. Herein, a simple electrodeposition combined with hydrothermal method is applied to synthesize a non-precious OER catalyst with a three-dimensional (3D) core-shell like structure and excellent OER performance. In our work, NiFe layered double hydroxide (LDH) was electrodeposited on Ni3S2nanosheets on nickel foam (NF), which exhibits a better performance compared with RuO2, and a low overpotential of 200 mV is needed to reach the current density of 10 mA/cm2in 1 M KOH. Notably, the Ni3S2/NiFe LDH only need an overpotential of 273 mV to reach the current density of 200 mA/cm2.
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