ELECTRON SPIN RESONANCE STUDY OF THE ELECTRON EXCHANGE BETWEEN NAPHTHALENE NEGATIVE ION AND NAPHTHALENE
ELECTRON SPIN RESONANCE STUDY OF THE ELECTRON EXCHANGE BETWEEN NAPHTHALENE NEGATIVE ION AND NAPHTHALENE
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DOI：
10.1021/ja01566a017
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发表时间：
1957-01-01
影响因子：
15
通讯作者：
WEISSMAN, SI
中科院分区：
文献类型：
--
作者：
WARD, RL;WEISSMAN, SI
由于最近发展了高分辨力的射频和微波光谱技术，在某些情况下，直接测定反应中参与者的生产率和消耗率已成为可能。测量依赖于这样一个事实，即与一对态之间的跃迁有关的光谱线的形状受态的平均寿命的影响。洛伦兹在处理碰撞对谱线宽度的影响时提出了寿命和谱线宽度之间关系的基本思想。8.许多作者还进一步提出，
Direct determination of rates of production and consumption of participants in a reaction has be-come possible in certain cases by the recent devel-opment of radiofrequency and microwave spec-troscopic techniques of high resolving power. The measurements depend on the fact that the shape of a spectroscopic line associated with a tran-sition between a pair of states is affected by the mean life ofthe states. The essential ideas involved in the relations between lifetimes and line breadths were worked out by Lorentz in his treatments of the effects of collisions on the breadth of spectral lines. 8 Many authors have further de-