Theory of isomerization equilibrium in electrophoresis. II.
Theory of isomerization equilibrium in electrophoresis. II.
复制标题
电泳中的异构化平衡理论。
DOI：
10.1016/s0003-9861(61)80055-6
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发表时间：
1961
影响因子：
3.9
通讯作者：
H. Bailey
中科院分区：
文献类型：
--
作者：
J. Cann;H. Bailey
用数值解法求解了描述双组分异构化体系AB电电泳输运的微分方程组。计算得到的纹影图案与Scholten(2)用另一种计算方法得到的纹影图案一致。结果的一个新特征是，在一定的反应速率和电泳时间条件下，纹影图案可能出现三个峰。
The system of differential equations describing the electroophoretic transport of two-component isomerizing systems, AB, has been solved by numerical solution of the corresponding difference equations. The calculated schlieren patterns agree with those obtained by Scholten (2) using a different method of computation. A novel feature of the results is that the schlieren patterns may show three peaks under certain conditions of rates of reaction and time of electrophoresis.