Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis
Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis
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DOI：
10.1039/c8qo00082d
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发表时间：
2018-05
影响因子：
5.4
通讯作者：
Xiaohong Pan;Yue‐wei Zhao;Hong-An Qu;Jin‐Hong Lin;Xiao-Chun Hang;Ji-Chang Xiao
中科院分区：
文献类型：
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作者：
Xiaohong Pan;Yue‐wei Zhao;Hong-An Qu;Jin‐Hong Lin;Xiao-Chun Hang;Ji-Chang Xiao
本文叙述了烯烃与硫盐(Ph2S+CH2RFTFO−)(Rf=CF3或HCF2)在可见光光氧化还原催化下的三氟乙基化或甲氧基三氟乙基化产物。研究发现，改变反应溶剂会导致反应路径的改变。
The tri- and di-fluoroethylation of alkenes with sulfonium salts, (Ph2S+CH2RF TfO−) (RF = CF3 or HCF2), by visible light photoredox catalysis to give tri-/di-fluoroethyl alkenes or methoxytri-/di-fluoroethylation products are described. It was found that varying the reaction solvent led to changes in the reaction path.