Dirhodium tetraprolinate-catalyzed asymmetric cycloproplanations with high turnover numbers
Dirhodium tetraprolinate-catalyzed asymmetric cycloproplanations with high turnover numbers
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DOI：
10.1021/ol034002a
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发表时间：
2003-05-01
期刊：
影响因子：
5.2
通讯作者：
Venkataramani, C
中科院分区：
文献类型：
--
作者：
Davies, HML;Venkataramani, C
桥接的四脯氨酸二钠Rh-2(S-biTISP)(2)(2)在室温下催化苯基重氮乙酸甲酯与苯乙烯之间的不对称环丙化反应，具有较高的周转率（92000）和周转率（4000 / h）。
graphicThe bridged dirhodium tetraprolinate Rh-2(S-biTISP)(2) (2) catalyzes the asymmetric cyclopropanation reaction between methyl phenyldiazoacetate and styrene at room temperature with high turnover number (92 000) and turnover frequency (4000 per h).