Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes
Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes
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铜介导的乙酸炔丙酯的三氟甲基化生成三氟甲基丙二烯
DOI：
10.1039/c3ob42575d
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发表时间：
2014-01-01
影响因子：
3.2
通讯作者：
Gu, Yu-Cheng
中科院分区：
文献类型：
--
作者：
Ji, Yun-Long;Kong, Jun-Jie;Gu, Yu-Cheng
介绍了一种铜催化的炔丙基乙酸酯与S-三氟甲基二苯基锍三氟甲磺酸盐的三氟甲基化反应，以中等至优异的产率得到三氟甲基化的联烯。
A copper-mediated trifluoromethylation of propargyl acetates with S-(trifluoromethyl)diphenylsulfonium triflate leading to trifluoromethylated allenes in moderate to excellent yields is described.