Observation of long-range f-f interactions between two f-electronic systems in quadruple-decker phthalocyanines
Observation of long-range f-f interactions between two f-electronic systems in quadruple-decker phthalocyanines
复制标题
DOI：
10.1039/c1cc14657b
复制
发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Ishikawa, Naoto
中科院分区：
文献类型：
--
作者：
Fukuda, Takamitsu;Kuroda, Wakako;Ishikawa, Naoto
合成了含稀土离子Tb ~（3+）、Dy ~（3+）、Er ~（3+）和Y ~（3+）的均相和杂相四层酞菁四聚体，并对其磁性进行了表征，证明了两个f电子中心之间的长程相互作用.
Homo and heteronuclear quadruple-decker phthalocyanine tetramers containing Y3+ and/or magnetically anisotropic lanthanide ions such as Tb3+, Dy3+, and Er3+ have been synthesized, and their magnetic properties have been elucidated, giving clear evidence of the long-range interactions between two f-electronic centers.