Smectic Aggregates of Sheet-Like Side-Chain Liquid Crystalline Polyacetylenes Directly Formed During Solution Polymerization

Smectic Aggregates of Sheet-Like Side-Chain Liquid Crystalline Polyacetylenes Directly Formed During Solution Polymerization
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溶液聚合过程中直接形成的片状侧链液晶聚乙炔的近晶聚集体

DOI:
10.1021/ma100619h
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发表时间:
2010-06
期刊:
影响因子:
5.5
通讯作者:
--
中科院分区:
化学1区
文献类型:
--
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我们已经成功地合成了两种侧链液晶聚乙炔(表示为P3-5和P2-5),其介晶单元基于“苯基-酯-苯基”基序以端接模式直接连接到半刚性聚乙炔主链,
We have successfully synthesized two side-chain liquid crystalline polyacetylenes (denoted as P3-5 and P2-5) with the mesogenic units based on a “phenyl−ester−phenyl” motif directly linked to the semirigid polyacetylene backbone in a terminal-on mode with