Ultrahard diamond single crystals from chemical vapor deposition

Ultrahard diamond single crystals from chemical vapor deposition
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DOI:
10.1002/pssa.200409033
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发表时间:
2004-03-01
影响因子:
2
通讯作者:
Hemley, RJ
Hemley, RJ
中科院分区:
材料科学4区
文献类型:
--
作者:
Yan, CS;Mao, HK;Hemley, RJ

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采用微波等离子体化学气相沉积(CVD)技术,以极高的生长速率制备出宝石级金刚石单晶,并发现其具有优异的力学性能。生长的材料具有极高的断裂韧性,并且通过高压/高温退火处理产生具有异常高的固有硬度的晶体。退火似乎诱导CVD单晶金刚石的一种新的加工硬化。(C)2004 WILEY-VCH Verlag GmbH & Co. KGaA,魏因海姆。
Gem-sized single crystals of diamond have been produced by very high growth rate microwave plasma chemical vapor deposition (CVD) and found to exhibit remarkable mechanical properties. The as-grown material has extremely high fracture toughness, and treatment by high-pressure/high-temperature annealing produces crystals that have exceptionally high intrinsic hardness. The annealing appears to induce a novel work hardening of CVD single-crystal diamond. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.