Fourier transform infrared study of tricarbon hydride radicals trapped in Ar at 10 K
Fourier transform infrared study of tricarbon hydride radicals trapped in Ar at 10 K
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10 K 下 Ar 中捕获的三碳氢化物自由基的傅里叶变换红外研究
DOI：
10.1063/1.459137
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发表时间：
1990
影响因子：
4.4
通讯作者：
W. Graham
中科院分区：
文献类型：
--
作者：
J. W. Huang;W. Graham
用傅里叶变换光谱法研究了10 K下真空紫外光下甲基乙炔和各种氘代同位素在氩气中的光解产物在200-3400 cm−1范围内的振动光谱。补充研究检查了丙二烯以及C3 H6和C3 D 6，环丙烷的光解产物。结果揭示了C3 H的振动的新信息;五个C3 H2异构体，环丙烯叉，乙烯基卡宾，三重炔丙基，反式和顺式丙烯二叉;两个C3 H3异构体，炔丙基和环丙烯基;和C3 H5，烯丙基。
The vibrational spectra of tricarbon hydride radicals formed by trapping the products of the vacuum ultraviolet photolysis of methylacetylene and various deuterated isotopomers in argon at 10 K have been investigated by Fourier transform spectroscopy in the range 200–3400 cm−1. Supplementary studies have examined the photolysis products of allene as well as C3H6 and C3D6, cyclopropane. The results reveal new information on the vibrations of C3H; five C3H2 isomers, cyclopropenylidene, vinylidenecarbene, triplet propargylene, trans‐ and cis‐propenediylidene; two C3H3 isomers, propargyl and cyclopropenyl; and C3H5, allyl.
DOI：
10.1086/184567
发表时间：
1985-11
期刊：
The Astrophysical journal
影响因子：
--
作者：
He Matthews;William M. Irvine
通讯作者：
He Matthews;William M. Irvine