Direct Arylation of HeteroarenesCatalyzed by a Palladium-1,10-PhenanthrolineComplex
Direct Arylation of HeteroarenesCatalyzed by a Palladium-1,10-PhenanthrolineComplex
复制标题
DOI：
10.1055/s-0030-1259727
复制
发表时间：
2011-04
期刊：
影响因子：
2
通讯作者：
Ryo Takita;D. Fujita;F. Ozawa
中科院分区：
文献类型：
--
作者：
Ryo Takita;D. Fujita;F. Ozawa
报道了以Pd(OAc)2和1，10-二氮杂菲为氮基配体的杂芳烃直接芳基化反应的新进展。通过对催化剂的改进，有效地缩短了反应初期较长的诱导期，提高了化学产率(69-92%)，缩短了反应时间(3-10小时)。
A new entry in direct arylation of heteroarenes using Pd(OAc) 2 and1,10-phenanthroline as a nitrogen-based ligand is reported. Thelong induction period observed at the initial stage of the reactionwas effectively reduced by modification of the catalyst preparation,leading to improved chemical yields (69-92%) and shorteningof reaction times (3-10 h).