Direct synthesis and structural characterisation of tri- and tetra-nuclear silver metallaknotanes by self-assembly approach
Direct synthesis and structural characterisation of tri- and tetra-nuclear silver metallaknotanes by self-assembly approach
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DOI：
10.1039/b815580a
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发表时间：
2008-01-01
影响因子：
4.9
通讯作者：
Hosseini, Mir Wais
中科院分区：
文献类型：
--
作者：
Bourlier, Julien;Jouaiti, Abdelaziz;Hosseini, Mir Wais
基于作为主要配位位点的两个喹啉单元的配体的组合，通过作为次要相互作用位点的四或五乙烯氧基片段连接，在银阳离子存在下在一锅反应中自发地形成三核和四核金属有机结。
The combination of ligands based on two quinoline units acting as primary coordinating sites connected by tetra- or penta-ethyleneoxy fragments behaving as secondary interaction sites leads spontaneously in a one-pot reaction to the formation of tri- and terta-nuclear metalla-organic knots in the presence of silver cation.