Study on morphology of ternary polymer blends. II. Effect of composition

Study on morphology of ternary polymer blends. II. Effect of composition
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DOI:
10.1002/app.1948
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发表时间:
2001-10
影响因子:
3
通讯作者:
M. Hemmati;H. Nazokdast;H. S. Panahi
M. Hemmati;H. Nazokdast;H. S. Panahi
中科院分区:
化学3区
文献类型:
--
作者:
M. Hemmati;H. Nazokdast;H. S. Panahi

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研究了组分对聚丙烯/乙丙二烯三元共聚物/聚乙烯(PP/EPDM/PE)和聚丙烯/乙丙二烯三元共聚物/聚苯乙烯(PP/EPDM/PS)三元共混物形貌的影响。在所有共混物中,聚丙烯作为主要相与两个次要相,即EPDM和PE或PS共混。通过使用扫描电镜技术的形态学研究,观察到PP/EPDM/PE的核壳形态和PP/EPDM/PS的分离分散形态。这些结果与理论预测一致。组分的组成只影响分散相的大小,对形貌类型没有明显的影响。每个分散相的大小,无论是形成核还是壳,还是单独分散在基体中,都可以直接关系到它在共混物中的组成。©2001 John Wiley & Sons, Inc应用化学学报,32 (2):398 - 398
The composition effect on morphology of polypropylene/ethylene–propylene–diene terpolymer/polyethylene (PP/EPDM/PE) and polypropylene/ethylene–propylene–diene terpolymer/polystyrene (PP/EPDM/PS) ternary blends has been investigated. In all of the blends, polypropylene as the major phase was blended with two minor phases, that is, EPDM and PE or PS. From morphological studies using the SEM technique a core–shell morphology for PP/EPDM/PE and separated dispersed morphology for PP/EPDM/PS were observed. These results were found to be in agreement with the theoretical predictions. The composition of components affected only the size of dispersed phases and had no appreciable effect on the type of morphology. The size of each dispersed phase, whether it forms core or shell or disperses separately in matrix, can be related directly to its composition in the blend. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 1138–1146, 2001