Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst
Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst
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DOI：
10.1039/a901678c
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发表时间：
1999-01-01
影响因子：
4.9
通讯作者：
Que, L
中科院分区：
文献类型：
--
作者：
Chen, K;Que, L
[Fe-II(bpmen)-(CH3CN)(2)](ClO4)(2)- h2o2对立体定向烷烃羟基化反应产物中(H2O)-O-18的加入，首次有力地证明了高价铁氧化物参与非血红素铁催化剂的机理。
The incorporation of O-18 from (H2O)-O-18 into the product of stereospecific alkane hydroxylation by [Fe-II(bpmen)-(CH3CN)(2)](ClO4)(2)-H2O2 provides the first strong evidence for the participation of a high-valent iron-oxo species in the mechanism of a non-heme iron catalyst.