Ru catalyzed hydrogenation of CO2 to formate under basic and acidic conditions
Ru catalyzed hydrogenation of CO2 to formate under basic and acidic conditions
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DOI：
10.1016/j.poly.2021.115375
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发表时间：
2021-07
期刊：
影响因子：
2.6
通讯作者：
Austin T Cannon;C. Saouma
中科院分区：
文献类型：
--
作者：
Austin T Cannon;C. Saouma
将CO2氢化为MeOH对于推进未来的能源计划是相关的。为此，膦连接的Ru催化剂已被证明在酸性或碱性条件下实现这种转化。在这篇手稿中，我们筛选催化条件的一种新的三（膦）配体与钌，看看它是否可以促进CO2转化为甲醇在酸性和碱性条件下。在这两组条件下，我们观察到CO2加氢生成甲酸盐。这项工作表明，相同的催化体系可以在两种反应类型下起作用，但仅限于甲酸盐的生产。
The hydrogenation of CO2to MeOH is pertinent to advance future energy schemes. Towards this end, phosophine-ligated Ru catalysts have been shown to achieve this transformation under either acidic or basic conditions. In this manuscript, we screen catalytic conditions for a novel tris(phosphine) ligand with Ru to see if it can facilitate the conversion of CO2to MeOH under both acidic and basic conditions. With both sets of conditions, we observe hydrogenation of CO2to formate. This work shows that the same catalytic system can function under both reaction types but is limited to formate production.