Use of dimethyl carbonate as a solvent greatly enhances the biaryl coupling of aryl iodides and organoboron reagents without adding any transition metal catalysts
Use of dimethyl carbonate as a solvent greatly enhances the biaryl coupling of aryl iodides and organoboron reagents without adding any transition metal catalysts
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DOI：
10.1039/c2cc17401d
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Doi, Takayuki
中科院分区：
文献类型：
--
作者：
Inamoto, Kiyofumi;Hasegawa, Chisa;Doi, Takayuki
芳基碘化物与芳基硼酸的偶联反应可以在不添加过渡金属催化剂的情况下有效地进行。成功的关键是使用碳酸二甲酯作为溶剂。这一发现为构建联芳键提供了一种新的策略。
The coupling reaction of aryl iodides with arylboronic acids to give biaryl compounds can be efficiently performed without adding a transition metal catalyst. The key to success is the use of dimethyl carbonate as a solvent. This finding provides a new strategy for constructing a biaryl linkage.