Synthesis of Aryldiazoacetates through Palladium(0)-Catalyzed Deacylative Cross-Coupling of Aryl Iodides with Acyldiazoacetates
Synthesis of Aryldiazoacetates through Palladium(0)-Catalyzed Deacylative Cross-Coupling of Aryl Iodides with Acyldiazoacetates
复制标题
钯(0)催化芳基碘化物与酰基重氮乙酸酯脱酰交叉偶联合成芳基重氮乙酸酯
DOI：
10.1002/anie.201407653
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发表时间：
2014
期刊：
影响因子：
--
通讯作者：
Jianbo Wang
中科院分区：
文献类型：
--
作者：
Fei Ye;Chengpeng Wang;Yan Zhang;Jianbo Wang
钯（0）催化的芳基碘和酰基重氮羰基化合物的脱酰基交叉偶联可以在室温下在温和的反应条件下实现。偶联反应代表了合成芳基重氮羰基化合物的高效和通用方法，其已经发现作为用于产生供体/受体取代的双卡宾的前体的广泛和越来越多的应用。
Palladium(0)‐catalyzed deacylative cross‐coupling of aryl iodides and acyldiazocarbonyl compounds can be achieved at room temperature under mild reaction conditions. The coupling reaction represents a highly efficient and general method for the synthesis of aryldiazocarbonyl compounds, which have found wide and increasing applications as precursors for generating donor/acceptor‐substituted metallocarbenes.