Crystal melting and glass formation in copper thiocyanate based coordination polymers
Crystal melting and glass formation in copper thiocyanate based coordination polymers
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DOI：
10.1039/c9cc02172h
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发表时间：
2019-05-11
影响因子：
4.9
通讯作者：
Horike, Satoshi
中科院分区：
文献类型：
--
作者：
Nagarkar, Sanjog S.;Kurasho, Haruna;Horike, Satoshi
配位聚合物（CPs）和金属有机骨架（MOFs）的晶体熔化和玻璃化是罕见的热事件。为了扩展熔融CP/MOFs库，我们利用离子液体中的反晶体工程来构建CP。Cu+和4，4-联吡啶-1-鎓衍生物的组合提供了四种熔融CP，显示出稳定的液体和玻璃态。
Crystal melting and glass formation of coordination polymers (CPs) and metal-organic frameworks (MOFs) are rare thermal events. To expand the library of melting CP/MOFs, we utilized anti-crystal engineering in ionic liquids to construct CPs. A combination of Cu+ and 4,4-bipyridin-1-ium derivatives afforded four melting CPs showing stable liquid and glassy states.