Recent advances in molecular rearrangements involving aryne intermediates.
Recent advances in molecular rearrangements involving aryne intermediates.
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DOI：
10.1039/c7cc09122b
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发表时间：
2018-03
影响因子：
4.9
通讯作者：
T. Roy;A. Biju
中科院分区：
文献类型：
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作者：
T. Roy;A. Biju
这篇专题文章旨在重点介绍无过渡金属的芳基分子重排的最新进展。在过去的三十年里，芳基炔的化学已经显示出令人难以置信的发展，特别是在无过渡金属的碳-碳和碳-杂原子键形成反应中。这一领域的快速发展主要是由于温和的方法产生的arynes。在芳炔化合物化学的最新发展的一个方面涉及通过这种亲电中间体进行的分子重排。分子重排提供了直接进入有价值分子库的途径，这是通过其他合成途径无法在一个步骤中获得的。在这里，我们提出了一个简明的帐户在这一领域发生的发展，在过去的三十年。
This Feature Article is aimed at highlighting the recent developments in the transition-metal-free molecular rearrangements involving arynes. The chemistry of arynes has shown incredible developments especially in transition-metal-free carbon-carbon and carbon-heteroatom bond-forming reactions in the last three decades. The rapid growth in this field is mainly due to the development of mild methods for the generation of arynes. One aspect of the recent developments in the chemistry of arynes involves the molecular rearrangements proceeding via this electrophilic intermediate. The molecular rearrangements have provided direct access to a library of valuable molecules, which cannot be accessed in a single step through other synthetic routes. Herein, we present a concise account on the developments that occurred in this field over the last three decades.