Alkene oligomerisation and polymerisation with metal-NHC based catalysts.
Alkene oligomerisation and polymerisation with metal-NHC based catalysts.
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DOI：
10.1039/b906479f
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发表时间：
2009-08
影响因子：
4
通讯作者：
D. McGuinness
中科院分区：
文献类型：
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作者：
D. McGuinness
N-杂环卡宾 (NHC) 的金属配合物目前在均相催化中普遍存在，但它们作为烯烃低聚和聚合催化剂的应用才刚刚兴起。近年来，一系列来自过渡系列和镧系元素的 NHC 配合物已作为烯烃聚合催化剂进行了测试，并得到了不同的结果。该观点详细介绍了自 1998 年以来该领域的研究，当时首次测试了金属-NHC 配合物用于烯烃聚合。
Metal complexes of N-heterocyclic carbenes (NHCs) are now ubiquitous in homogeneous catalysis, yet their use as catalysts for oligomerisation and polymerisation of alkenes is only now gaining momentum. In recent years, a range of NHC complexes from across the transition series, and from the lanthanides, have been tested as alkene polymerisation catalysts with varying results. This perspective details the research in this field since 1998, when metal-NHC complexes were first tested for alkene polymerisation.