Solvent effects on thermodynamic parameters for porphyrin–quinone interaction through multiple hydrogen bonding

Solvent effects on thermodynamic parameters for porphyrin–quinone interaction through multiple hydrogen bonding
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溶剂对通过多重氢键的卟啉-醌相互作用的热力学参数的影响

DOI:
10.1039/a704107a
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发表时间:
1997
影响因子:
4.9
通讯作者:
Takashi Hayashi
Takashi Hayashi
中科院分区:
化学2区
文献类型:
--
作者:
Takashi Hayashi

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在甲苯-乙醇二元溶剂中,非共价连接的卟啉-醌络合反应的熵-熵补偿图显示出不同极性下的ΔH°与TΔS°之间的非线性钩状关系。
The enthalpy–entropy compensation plots for noncovalently linked porphyrin–quinone complexation exhibit a non-linear hook-shaped relationship between ΔH° and TΔS° at various polarities in a toluene–ethanol binary solvent.
DOI: 10.1021/ja00058a068
发表时间: 1993-03
影响因子: 15
作者:
Takashi Hayashi;T. Miyahara;N. Hashizume;H. Ogoshi
通讯作者: Takashi Hayashi;T. Miyahara;N. Hashizume;H. Ogoshi