Synthesis of Novel Alternating π-Conjugated Copolymers Having [2.2]Paracyclophane and Fluorene Units in the Main Chain Leading to the Blue Light-Emitting Materials

Synthesis of Novel Alternating π-Conjugated Copolymers Having [2.2]Paracyclophane and Fluorene Units in the Main Chain Leading to the Blue Light-Emitting Materials
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主链上具有[2.2]对环芳烷和芴单元的新型交替π-共轭共聚物的合成,产生蓝色发光材料

DOI:
10.1246/cl.2002.194
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发表时间:
2002
期刊:
影响因子:
1.6
通讯作者:
Y. Chujo
Y. Chujo
中科院分区:
化学4区
文献类型:
--
作者:
Y. Morisaki;Y. Chujo

文献摘要

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通过Heck-Sonogashira偶联反应合成了一种新型的具有[2.2]对环番和荧烯单元的全空间π共轭聚合物。聚合物在溶液和固体中都表现出很强的蓝色荧光。
Novel through-space π-conjugated polymers having [2.2]paracyclophane and fluorene units were synthesized by Heck-Sonogashira coupling reaction. The polymers exhibited strong blue fluorescence in solution and in the solid state.