Ion imprinted polymer based potentiometric sensor for the trace determination of Cadmium (II) ions
Ion imprinted polymer based potentiometric sensor for the trace determination of Cadmium (II) ions
复制标题
DOI：
10.1016/j.arabjc.2012.12.021
复制
发表时间：
2017-02-01
影响因子：
6
通讯作者：
Ashraf, Narges
中科院分区：
文献类型：
--
作者：
Ivari, Seyyed Ahmad Rezvani;Darroudi, Abolfazl;Ashraf, Narges
以离子印迹聚合物（IIP）为载体，制备了镉离子选择性电极（伊势）。离子选择性电极（伊势）的制备方法是将镉（II）IIP颗粒分散在作为增塑剂的2-硝基苯辛基醚中，然后将其包埋在聚氯乙烯聚合物基体中。在2.0 x 10（-7）-1.0 x 10（-2）mol L-1的动态浓度范围内，Cd（II）伊势选择电极对Cd（II）呈现能斯特响应，斜率为29.9 mV/decade。检测限为1.0 × 10（-7）M。所提出的电极表现出良好的选择性，在各种各样的其他阳离子，包括碱金属，碱土金属，重金属和过渡金属。通过对加标水样的分析，检查了拟定电极的准确度。(C)2013年由Elsevier B. V.代表沙特国王大学制作和主持。
A cadmium (II) ion selective electrode (ISE) based on an ion-imprinted polymer (IIP) as a novel ionophore has been prepared and studied. The ion-selective electrode (ISE) was prepared by dispersing cadmium (II) IIP particles in 2-nitrophenyloctyl ether as a plasticizer and then embedding them in a polyvinylchloride polymeric matrix. The Cd(II) ISE showed a nernstian response for cadmium (II) over the dynamic concentration range of 2.0 x 10(-7)-1.0 x 10(-2) mol L-1, with a slope of 29.9 mV per decade. The limit of detection was 1.0 x 10(-7) M. The proposed electrode revealed good selectivity over a wide variety of other cations including alkali, alkaline earth, heavy and transition metals. The accuracy of the proposed electrode was checked through the analysis of spiked water samples. (C) 2013 Production and hosting by Elsevier B.V. on behalf of King Saud University.