Synthesis and Characterization of Teranthene: A Singlet Biradical Polycyclic Aromatic Hydrocarbon Having Kekule Structures
Synthesis and Characterization of Teranthene: A Singlet Biradical Polycyclic Aromatic Hydrocarbon Having Kekule Structures
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DOI：
10.1021/ja1049737
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发表时间：
2010-08-18
影响因子：
15
通讯作者：
Kubo, Takashi
中科院分区：
文献类型：
--
作者：
Konishi, Akihito;Hirao, Yasukazu;Kubo, Takashi
首次成功地分离出了一种结晶形式的特蒽衍生物。几何构型和物理性质研究表明，该分子在基态具有明显的双自由基性质。
A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.