Regioselective radical hydroboration of electron-deficient alkenes: synthesis of α-boryl functionalized molecules
Regioselective radical hydroboration of electron-deficient alkenes: synthesis of α-boryl functionalized molecules
复制标题
缺电子烯烃的区域选择性自由基硼氢化：α-硼基官能化分子的合成
DOI：
10.1039/c9cc06506g
复制
发表时间：
2019-10-11
影响因子：
4.9
通讯作者：
Wang, Yi-Feng
中科院分区：
文献类型：
--
作者：
Huang, Yun-Shuai;Wang, Jie;Wang, Yi-Feng
各种缺电子烯烃的区域选择性自由基硼化是通过使用nhc -硼基自由基来实现的。一系列的-硼化腈、三氟甲基分子、膦酸盐、砜和宝石二硼化合物已经从现成的原料中制备出来。进一步的合成应用这些产品也证明了。
A regioselective radical hydroboration of various electron-deficient alkenes is achieved by the employment of an NHC-boryl radical. A range of alpha-borylated nitriles, trifluoromethyl molecules, phosphonates, sulfones, and gem-diboron compounds have been prepared from readily available starting materials. Further synthetic applications of these products are also demonstrated.