Hybrid Organic-Inorganic Rotaxanes, Including a Hetero-Hybrid [3]Rotaxane Featuring Two Distinct Heterometallic Rings and a Molecular Shuttle.
Hybrid Organic-Inorganic Rotaxanes, Including a Hetero-Hybrid [3]Rotaxane Featuring Two Distinct Heterometallic Rings and a Molecular Shuttle.
复制标题
DOI：
10.1002/anie.201805439
复制
发表时间：
2018-07
影响因子：
--
通讯作者：
G. Timco;Antonio Fernandez;A. Kostopoulos;Jodie F. Charlton;Selena J Lockyer;Thomas R. Hailes;R. W. Adams;E. McInnes;F. Tuna;I. Vitorica-Yrezabal;G. Whitehead;R. Winpenny
中科院分区：
文献类型：
--
作者：
G. Timco;Antonio Fernandez;A. Kostopoulos;Jodie F. Charlton;Selena J Lockyer;Thomas R. Hailes;R. W. Adams;E. McInnes;F. Tuna;I. Vitorica-Yrezabal;G. Whitehead;R. Winpenny
[2]和[3]杂化轮烷基于{Ti7 M}环（M是一种三价金属，如FeIII或GaIII）。核磁共振研究表明[2]轮烷可以作为分子穿梭体，而EPR研究表明[3]轮烷的超分子组装体的顺磁性组分之间存在弱相互作用。
[2] and [3] hybrid rotaxanes are reported based on {Ti7 M} rings (M is a trivalent metal such as FeIII or GaIII ). NMR studies show that [2]rotaxanes can act as molecular shuttles, while EPR studies of [3]rotaxanes show weak interactions between the paramagnetic components of the supramolecular assemblies.