Cooperative Heterobimetallic Substrate Activation Enhances Catalytic Activity and Amplifies Regioselectivity in 1,4-Hydroboration of Pyridines
Cooperative Heterobimetallic Substrate Activation Enhances Catalytic Activity and Amplifies Regioselectivity in 1,4-Hydroboration of Pyridines
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DOI：
10.1021/acscatal.0c00515
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发表时间：
2020-02
期刊：
影响因子：
12.9
通讯作者：
Hsien‐Cheng Yu;S. Islam;Neal P. Mankad
中科院分区：
文献类型：
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作者：
Hsien‐Cheng Yu;S. Islam;Neal P. Mankad
研究了异双核催化剂（IPr）CuFeCp（CO）2在吡啶衍生物和喹啉与频哪醇硼烷的1，4-硼氢化反应中的催化活性。
Regioselective 1,4-hydroboration of pyridine derivatives and quinoline with pinacolborane is catalyzed efficiently by the heterobinuclear catalyst, (IPr)CuFeCp(CO)2, at only 2 mol % loading, provid...