Isolation and Identification of the Female Sex Pheromone of the Potato Tuberworm Moth, Phthorimaea operculella (Zeller)
Isolation and Identification of the Female Sex Pheromone of the Potato Tuberworm Moth, Phthorimaea operculella (Zeller)
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马铃薯块茎蛾Phthorimaea operculella (Zeller)雌性性信息素的分离与鉴定
DOI：
10.1271/bbb1961.40.1971
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发表时间：
1976
期刊：
影响因子：
--
通讯作者：
S. Ishii
中科院分区：
文献类型：
--
作者：
R. Yamaoka;H. Fukami;S. Ishii
从实验室饲养的未交配雌蛾中分离到马铃薯夜蛾成虫产生的性信息素。气相色谱和质谱学数据表明，该信息素为十三碳三烯基乙酸酯。分离的信息素用肼和过氧化氢进行部分氢化，然后臭氧分解，生成ω-乙酰氧基-烷烃的混合物。经质谱鉴定为4-乙酰氧基丁醛、7-乙酰氧基庚醛和10-乙酰氧基正庚醛。因此，除几何构型外，该信息素被鉴定为4，7，10-十三碳三烯乙酸酯。
The sex pheromone produced by adult females of the potato tuberworm moth was isolated from unmated female moths reared in the laboratory. The gas Chromatographic and mass spectrometric data suggested the pheromone to be a tridecatrienyl acetate. The isolated pheromone was subjected to partial hydrogenation with hydrazine and hydrogen peroxide and subsequent ozonolysis to produce a mixture of ω-acetoxy-alkanals. They were identified by mass Chromatographic technique as 4-acetoxy-butanal, 7-acetoxy-heptanal, and 10-acetoxy-decanal respectively. Consequently, the pheromone was identified as 4,7,10-tridecatrienyl acetate except the geometric configuration.