Cover Feature: Stopped-Flow 19 F NMR Spectroscopic Analysis of a Protodeboronation Proceeding at the Sub-Second Time-Scale (Eur. J. Org. Chem. 17/2021)
Cover Feature: Stopped-Flow 19 F NMR Spectroscopic Analysis of a Protodeboronation Proceeding at the Sub-Second Time-Scale (Eur. J. Org. Chem. 17/2021)
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封面专题：亚秒级时间尺度的原脱硼过程的停流 19 F NMR 光谱分析（Eur. J. Org. Chem. 17/2021）
DOI：
10.1002/ejoc.202100467
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发表时间：
2021
影响因子：
2.8
通讯作者：
Wei R
中科院分区：
文献类型：
--
作者：
Wei R
封面特写展示了一位年轻的研究人员在核磁共振光谱仪的陪同下眺望浩瀚星空。流星代表了快速不可逆化学反应中嵌入的短暂信息，例如，五氟苯基硼酸的碱催化脱硼反应，其半衰期为0.12秒。借助停流NMR技术，研究人员能够从快速发展的反应中捕获信息，以获得有助于阐明反应机制的信息。更多信息可以在GC Bord-Jones等人的论文全文中找到。
The Cover Feature shows a young researcher looking into the vast starry sky, accompanied by an NMR spectrometer. The shooting stars represent the fleeting information embedded in rapid irreversible chemical reactions, for example, the base-catalyzed protodeboronation of penta-fluorophenyl boronic acid which has a half-life of 0.12 s. With the aid of a stopped-flow NMR technique, the researcher is able to capture the information from the rapidly evolving reactions, to gain information that will shed light on the reaction mechanism. More information can be found in the Full Paper by GC Lloyd-Jones et al.