Convex–convex and concave–convex interactions between C 60 and non-planar aromatic subphthalocyanine macrocycle in both covalent and supramolecular arrays

Convex–convex and concave–convex interactions between C 60 and non-planar aromatic subphthalocyanine macrocycle in both covalent and supramolecular arrays
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共价和超分子阵列中 C 60 和非平面芳香亚酞菁大环之间的凸-凸和凹-凸相互作用

DOI:
10.1016/j.crci.2005.12.006
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发表时间:
2006
期刊:
影响因子:
--
通讯作者:
T. Torres
T. Torres
中科院分区:
--
文献类型:
--
作者:
C. Claessens;D. González‐Rodríguez;R. Iglesias;T. Torres

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亚酞菁是一种弯曲的芳香大环,因其优异的光物理和电化学性能而被合成和研究。这个c3对称分子的曲率定义了非常有趣的凹π面和凸π面。本文综述了本课课组在c60富勒烯的凸π面与亚酞菁部分的凸或凹芳香面结合的共价和非共价系综合成方面的最新进展。引用本文:C.G. Claessens等,c.r. Chimie 9(2006)。
Subphthalocyanines are curved aromatic macrocycles that are being synthesized and studied for their excellent photophysical and electrochemical properties. The curvature of this C3symmetrical molecule defines very interesting concave and convex π-surfaces. This review article gives an updated overview of the efforts made in our research group in the synthesis of covalent and non-covalent ensembles that bring together the convex π-surface of C60fullerene and the convex or concave aromatic surfaces of a subphthalocyanine moiety. To cite this article: C.G. Claessens et al., C. R. Chimie 9 (2006).