Preparation of new triple-bridged dimers of ruthenium(II) by protonation of basic ruthenium hydrides with the weak acids HX (X = OH, SH, SMe, or F); X-ray crystal and molecular structure of [Ru2(OH)3(PMe2Ph)6][BPh4]
Preparation of new triple-bridged dimers of ruthenium(II) by protonation of basic ruthenium hydrides with the weak acids HX (X = OH, SH, SMe, or F); X-ray crystal and molecular structure of [Ru2(OH)3(PMe2Ph)6][BPh4]
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DOI：
10.1039/c39770000936
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发表时间：
1977
期刊：
影响因子：
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通讯作者：
T. V. Ashworth;M. Nolte;E. Singleton
中科院分区：
文献类型：
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作者：
T. V. Ashworth;M. Nolte;E. Singleton
[RuH（cod）L_3]~+[L = PMe_2Ph，PMePh_2，或P（OMe）Ph_2; cod =环辛烯]在丙酮-甲醇溶液中与HX（X = OH，SH，SMe，I，或F）反应生成[Ru_2X_3L_6]~+，测定了[Ru_2（OH）_3（PMe_2Ph）_6][BPh_4]的X射线结构，并讨论了某些二聚体的进一步反应。
Solutions containing [RuH(cod)L3]+[L = PMe2Ph, PMePh2, or P(OMe)Ph2; cod = cyclo-octadiene] in refluxing acetone–methanol produce [Ru2X3L6]+ with HX (X = OH, SH, SMe, I, or F); the X-ray structure of [Ru2(OH)3(PMe2Ph)6][BPh4] has been determined and further reactions of some of the dimers are discussed.