Isostructural Mesoporous Ionic Crystals as a Tunable Platform for Acid Catalysis
Isostructural Mesoporous Ionic Crystals as a Tunable Platform for Acid Catalysis
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同结构介孔离子晶体作为酸催化的可调平台
DOI：
10.1039/d0dt01202e
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发表时间：
2020
期刊：
影响因子：
--
通讯作者：
S. Uchida
中科院分区：
文献类型：
--
作者：
Y. Shimoyama;Z. Weng;N. Ogiwara;T. Kitao;Y. Kikukawa;S. Uchida
合成了11种同结构的介孔离子晶体。meso-PIC催化的Barbier-Grignard反应是一种典型的C-C键形成反应，其初始活性取决于构成meso-PIC的Mn ~+水溶液的酸解离常数和聚氧乙烯酸盐的种类。
Eleven isostructural mesoporous ionic crystals (meso–PICs) are synthesized. The initial activities of the Barbier-Grignard reaction, which is a typical C–C bond formation reaction, catalyzed by the meso-PICs are dependent on the acid dissociation constant of the aqua ions of Mn+ and the types of polyoxometalates, which construct the meso-PICs.