C(3) Functional Derivatives of the Blatter Radical.
C(3) Functional Derivatives of the Blatter Radical.
复制标题
C(3) 布拉特自由基的功能衍生物。
作者：
Dominika Pomikło;A. Bodzioch;A. Pietrzak;P. Kaszyński
将PhLi加入到3-取代苯并[e][1,2,4]三嗪2中，然后气氧化制得一系列3-取代1-苯基-1,4-二氢苯并[e][1,2,4]三嗪-4-酰1。研究了C(3)取代基在反应中的作用范围，分离出了10个结构多样的自由基，并用光谱和电化学方法对它们的稳定性和性质进行了评价。用单晶XRD分析了两种自由基。实验数据与DFT结果进行了比较，并与哈米特取代基参数进行了关联。
A series of 3-substituted 1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yls 1 was prepared by addition of PhLi to 3-substituted benzo[e][1,2,4]triazines 2 followed by aerial oxidation. The scope of the C(3) substituents in the reaction was investigated, and 10 structurally diverse radicals 1 were isolated, their stability was assessed and properties were investigated with spectroscopic and electrochemical methods. Two radicals were analyzed with single-crystal XRD methods. Experimental data are compared to DFT results and correlated with Hammett substituent parameters.
影响因子：
4.9
作者：
Constantinides, Christos P.;Carter, Emma;Koutentis, Panayiotis A.
通讯作者：
Koutentis, Panayiotis A.