Polyelectrolytes: On the doorsteps of the second century
Polyelectrolytes: On the doorsteps of the second century
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DOI：
10.1016/j.polymer.2020.122714
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发表时间：
2020-08-12
期刊：
影响因子：
4.6
通讯作者：
Dobrynin, Andrey V.
中科院分区：
文献类型：
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作者：
Dobrynin, Andrey V.
聚电解质是具有可电离基团的高分子。从这个角度来看，我将介绍一个简短的历史，从开创性的论文发表在20世纪上半叶的世纪，其次是目前的发展领域，并通过列表的常设问题。特别强调的是，将如何静态和动态性能取决于离解的离子基团，聚合物主链的溶剂质量，盐和聚合物浓度的分数的pH2.5解决方案。
Polyelectrolytes are macromolecules with ionizable groups. In this perspective, I will present a brief history of polyelectrolytes starting from the seminal papers published in the first half of the 20th century followed by the current developments in the field and by the list of the standing problems. Particular emphasis will be on how static and dynamic properties of polyelectrolyte solutions depend on the fraction of dissociated ionic groups, solvent quality for the polymer backbone, and salt and polymer concentrations.