Pcu versus lim nets: topological variation of cyano-bridged copper(I)-tetrazole coordination frameworks caused by Cu2(azole)2-SBU versatility

Pcu versus lim nets: topological variation of cyano-bridged copper(I)-tetrazole coordination frameworks caused by Cu2(azole)2-SBU versatility
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DOI:
10.1039/b806768f
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发表时间:
2008-07
期刊:
影响因子:
3.1
通讯作者:
Zhen Li;Mian Li;S. Zhan;Xiao-Chun Huang;S. Ng,;Dan Li
Zhen Li;Mian Li;S. Zhan;Xiao-Chun Huang;S. Ng,;Dan Li
中科院分区:
化学3区
文献类型:
--
作者:
Zhen Li;Mian Li;S. Zhan;Xiao-Chun Huang;S. Ng,;Dan Li

文献摘要

被引文献

相似文献

Cu2(azole)2-SBU通过原位溶(水)热合成,在氰基桥接的铜(I)-四唑配位框架的构建中说明了(二级结构单元)的多功能性,产生具有共同的非互穿3D pcu网的{[Cu 2(μ3-Mtta)2(CN)][Na(CH 3CN)]}n(1)和{[Cu 4(μ3-HMtta)2(CN)3](OH)}n(2),具有前所未有的四重互穿3D lim网。
The Cu2(azole)2-SBU (secondary building unit) versatility is illustrated in the construction of cyano-bridged copper(I)-tetrazole coordination frameworks through in situsolvo(hydro)thermal syntheses, yielding {[Cu2(μ3-Mtta)2(CN)][Na(CH3CN)]}n (1), with a common non-interpenetrated 3D pcu net, and {[Cu4(μ3-HMtta)2(CN)3](OH)}n (2), with an unprecedented four-fold interpenetrated 3D lim net.