Organization of zeolite microcrystals for production of functional materials.
Organization of zeolite microcrystals for production of functional materials.
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DOI：
10.1021/ar000119c
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发表时间：
2007
影响因子：
18.3
通讯作者：
K. B. Yoon
中科院分区：
文献类型：
--
作者：
K. B. Yoon
本文总结了将沸石微晶组织成二维功能实体(如各种基质上的单层、多层和图案化的单分子层)和三维功能实体(如微球和蛋白质-沸石复合纤维)的各种方法。在单层组装的情况下，描述了各种类型的键和衬底，控制速率、覆盖程度、紧密堆积程度、均匀取向程度以及每个晶体与衬底之间的平均结合强度的因素。并对有序产品的应用现状和前景进行了展望。
This Account summarizes various methods of organizing zeolite microcrystals into two-dimensional functional entities such as monolayers, multilayers, and patterned monolayers on various substrates and three-dimensional functional entities such as microballs and protein-zeolite composite fibrils. In the case of monolayer assembly, various types of linkages and substrates, factors that govern the rate, degree of coverage, degree of close packing, degree of uniform orientation, and average binding strength between each crystal and the substrate are described. The current and future applications of the organized products are also discussed.