New observations of structural diversity in copper(II) complexes of diphenylsulfimide
New observations of structural diversity in copper(II) complexes of diphenylsulfimide
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二苯基硫酰亚胺铜(II)配合物结构多样性的新观察
DOI：
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发表时间：
2006
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通讯作者：
M. Elsegood
中科院分区：
文献类型：
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作者：
K. E. Holmes;P. Kelly;S. H. Dale;M. Elsegood
S，S′-二苯基硫酰亚胺Ph 2SNH（1）与Cu[BF 4]2在乙腈中反应生成溶液，从中可以结晶出六种产物：[Cu（Ph 2SNH）4][BF 4]2的两种多晶型物，互配位[Cu（Ph 2SNH）4]2[BF 4]4，混合配位体系[Cu（Ph 2SNH）4][Cu（Ph 2SNH）5][BF 4]4，五配位[Cu（Ph 2SNH）5][BF 4]4（2）和腈加合物[Cu（Ph 2SNH）3（Ph 2SNC（Me）NH）][BF 4]2（3）。在高氯酸盐[Cu（Ph 2SNH）4][ClO 4]2（4）和[Cu（Ph 2SNH）4]2[ClO 4]4（5）以及硝酸盐[Cu（Ph 2SNH）4][NO3]2（6）和[Cu（Ph 2SNH）4][Cu（Ph 2SNH）5][NO3]4（7）中也观察到了很大的结构多样性。
Reaction of S,S′-diphenylsulfimide, Ph2SNH (1), with Cu[BF4]2 in acetonitrile generates a solution from which six products may be crystallised: two polymorphs of [Cu(Ph2SNH)4][BF4]2, the inter-allogon [Cu(Ph2SNH)4]2[BF4]4, the mixed coordination system [Cu(Ph2SNH)4][Cu(Ph2SNH)5][BF4]4, five-coordinate [Cu(Ph2SNH)5][BF4]4 (2) and the nitrile adduct [Cu(Ph2SNH)3(Ph2SNC(Me)NH)][BF4]2 (3). Great structural diversity is also observed in the perchlorate [Cu(Ph2SNH)4][ClO4]2 (4) and [Cu(Ph2SNH)4]2[ClO4]4 (5) and nitrate [Cu(Ph2SNH)4][NO3]2 (6) and [Cu(Ph2SNH)4][Cu(Ph2SNH)5][NO3]4 (7) salts.