The functionalization of saturated hydrocarbons. Part 20. Alkyl hydroperoxides: reaction intermediates in the oxidation of saturated hydrocarbons by Gif-type reactions and mechanistic studies on their formation
The functionalization of saturated hydrocarbons. Part 20. Alkyl hydroperoxides: reaction intermediates in the oxidation of saturated hydrocarbons by Gif-type reactions and mechanistic studies on their formation
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饱和烃的官能化。
DOI：
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发表时间：
1992
期刊：
影响因子：
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通讯作者：
Wan
中科院分区：
文献类型：
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作者：
D. Barton;S. Bévière;W. Chavasiri;É. Csuhai;D. Doller;Wan
提出了化学和13 C和2 H NMR光谱证据，证明仲烷基过氧化氢是GoAgg II条件下饱和烃氧化反应的反应中间体（氯化铁，过氧化氢在吡啶-乙酸溶液中）
Chemical and 13 C and 2 H NMR spectroscopic evidence is presented, proving that secondary alkyl hydroperoxides are reaction intermediates in the oxidation of saturated hydrocarbons under GoAgg II conditions (ferric chloride, hydrogen peroxide in pyridine-acetic acid solution)