catena-Poly­[[dicyan­amido(1,10-phen­anthroline)copper(II)]-μ-dicyan­amido]

catena-Poly­[[dicyan­amido(1,10-phen­anthroline)copper(II)]-μ-dicyan­amido]
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链状聚[[二氰胺基(1,10-菲咯啉)铜(II)]-μ-二氰胺基]

DOI:
10.1107/s0108270100004984
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发表时间:
2000
期刊:
Acta Crystallographica Section C-crystal Structure Communications
影响因子:
--
通讯作者:
Chunsheng Liao
Chunsheng Liao
中科院分区:
--
文献类型:
--
作者:
Zheming Wang;Jun Luo;Baiwang Sun;Chunhua Yan;Song Gao;Chunsheng Liao

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标题化合物[Cu(C2 N3)2(C12 H8 N2)]n是由[Cu(phen)(dca)2]n(phen为1,10-菲咯啉,dca为双氰胺)链通过二级Cu-N长键连接而成的片状结构。Cu ~(2+)处于畸变的四配位双锥(5 + 1)配位环境。  通过相邻片的配位phen配体之间的芳族相互作用,片堆叠成三维晶体结构。
The title compound, [Cu(C2N3)2(C12H8N2)]n, has a sheet-like structure, built by [Cu(phen)(dca)2]n (phen is 1,10-phenanthroline and dca is dicyan­amide) chains which are interconnected by secondary long Cu—N bonds between the chains. The Cu2+ ion is in a distorted tetragonal bipyramidal (5 + 1) coordination environment. The sheets stack into the three-dimensional crystal structure through aromatic interactions between the coordinated phen ligands of adjacent sheets.
DOI: 10.1107/s0108767394005726
发表时间: 1995-01-01
期刊: ACTA CRYSTALLOGRAPHICA SECTION A
影响因子: --
作者:
BLESSING, RH
通讯作者: BLESSING, RH