Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalyzed reaction of alkynyltriarylborates with aryl halides

Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalyzed reaction of alkynyltriarylborates with aryl halides
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DOI:
10.1039/b710472c
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发表时间:
2007-01-01
影响因子:
4.9
通讯作者:
Murakami, Masahiro
Murakami, Masahiro
中科院分区:
化学2区
文献类型:
--
作者:
Ishida, Naoki;Miura, Tomoya;Murakami, Masahiro

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炔基三芳基硼酸酯与芳基卤化物的钯催化反应得到三取代烯基硼烷,其中两个不同的芳基以顺式排列安装在碳碳双键上。
The palladium-catalysed reaction of alkynyltriarylborates with aryl halides afforded trisubstituted alkenylboranes, in which two different aryl groups were installed across the carbon carbon double bond in a cis arrangement.