Stereoselective cis-addition of aromatic C-H bonds to alkynes catalyzed by dinuclear palladium complexes.
Stereoselective cis-addition of aromatic C-H bonds to alkynes catalyzed by dinuclear palladium complexes.
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DOI：
10.1021/ja0375075
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发表时间：
2003-09
影响因子：
15
通讯作者：
Naofumi Tsukada;Tomohiro Mitsuboshi;Hiroyuki Setoguchi;Y. Inoue
中科院分区：
文献类型：
--
作者：
Naofumi Tsukada;Tomohiro Mitsuboshi;Hiroyuki Setoguchi;Y. Inoue
Reactions of alkynes with arenes proceeded in the presence of dinuclear palladium complexes and trialkylboranes to yield alkyne hydroarylation products with high stereoselectivity. In the reactions of monosubstituted benzenes, meta and para products were formed in statistical ratios, while no ortho isomers were detected.
