Ruthenium-Catalyzed C-H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles
Ruthenium-Catalyzed C-H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles
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DOI：
10.1021/ol3000876
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发表时间：
2012-02-17
期刊：
影响因子：
5.2
通讯作者：
Manvar, Atul
中科院分区：
文献类型：
--
作者：
Ackermann, Lutz;Diers, Emelyne;Manvar, Atul
钌催化的带有可去除的导向基团的苯酚直接芳基化反应是通过羧酸酯的辅助作用，以六元杂环为关键中间体完成的。
Ruthenium-catalyzed direct arylations of phenols bearing removable directing groups were accomplished through carboxylate assistance via six-membered ruthenacycles as key intermediates.