Bandgap determination of P(VDF-TrFE) copolymer film by electron energy loss spectroscopy

Bandgap determination of P(VDF-TrFE) copolymer film by electron energy loss spectroscopy
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DOI:
10.1007/s12034-010-0070-4
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发表时间:
2010-08-01
影响因子:
1.8
通讯作者:
Schmeisser, D.
Schmeisser, D.
中科院分区:
材料科学4区
文献类型:
--
作者:
Mandal, Dipankar;Henkel, K.;Schmeisser, D.

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对于100 nm厚的旋涂共聚物膜,证实了聚(偏二氟乙烯三氟乙烯)P(VDF-TrFE)的铁电β。借助X射线光电子能谱(XPS)研究了共聚物膜的均匀覆盖性。最重要的是,在共聚物的结晶相中存在的带隙直接由电子能量损失谱(EELS)确定。
The ferroelectric beta of poly(vinylidene fluoride trifluoroethylene), P(VDF-TrFE) is confirmed for 100 nm thickness spin coated copolymer film. The homogeneous coverage of the copolymer film is investigated by the help of X-ray photoelectron spectroscopy (XPS). Most importantly, the existing bandgap in the crystalline phase of the copolymer is determined directly from the electron energy loss spectroscopy (EELS).