Strained silacycles in organic synthesis: A new reagent for the enantioselective allylation of aldehydes
Strained silacycles in organic synthesis: A new reagent for the enantioselective allylation of aldehydes
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DOI：
10.1021/ja0264908
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发表时间：
2002-07-10
影响因子：
15
通讯作者：
Leighton, JL
中科院分区：
文献类型：
--
作者：
Kinnaird, JWA;Ng, PY;Leighton, JL
开发了一种用于脂肪醛对映选择性烯丙基化的新试剂。该试剂可以通过市售材料轻松一步制备，并且可以储存而不会明显分解。该试剂的反应性归因于应变释放路易斯酸度。
A new reagent for the enantioselective allylation of aliphatic aldehydes has been developed. The reagent is easily prepared in a single step from commercially available materials and may be stored without significant decomposition. The reactivity of the reagent is attributed to strain-release Lewis acidity.